The Nuclear Heat-Based Cu–Cl Hydrogen Facility

Source: PIB

Subject: Science and Technology

Context: The Department of Atomic Energy (DAE) has inaugurated the world’s first nuclear heat-based hydrogen production facility at IGCAR, Kalpakkam, Tamil Nadu.

  • It uses heat from the Fast Breeder Test Reactor (FBTR) to produce hydrogen through an indigenous Copper–Chlorine (Cu–Cl) thermochemical water-splitting process.

The Nuclear Heat-Based Cu–Cl Hydrogen Facility
The Nuclear Heat-Based Cu–Cl Hydrogen Facility

About The Nuclear Heat-Based Cu–Cl Hydrogen Facility:

What It Is?

  • The facility is a pioneering, carbon-free technology demonstrator that bridges nuclear engineering and chemical looping to generate clean hydrogen. Rather than relying on power-hungry water electrolysis, it directly consumes high-temperature volcanic-scale process heat from a nuclear core to chemically split water into hydrogen and oxygen.

Collaborative Development:

The facility represents an absolute triumph of indigenous multi-agency coordination:

  • The Core Technology: The Copper–Chlorine (Cu–Cl) thermochemical chemical cycle was conceptualized and developed indigenously by the Bhabha Atomic Research Centre (BARC) in Mumbai.
  • The Reactor Interface & Commissioning: The structural design, interface fabrication, and site-level commissioning were executed jointly by BARC and IGCAR at Kalpakkam.

Aim:

  • To advance India’s signature three-stage nuclear power programme by establishing a non-electric, industrial application for fast breeder reactors.
  • To demonstrate a highly continuous, scalable, and climate-neutral pathway to support India’s long-term energy security and clean hydrogen production goals.

How the Cu–Cl Thermochemical Cycle Works?

  • Hydrogen Production: Copper (Cu) reacts with dry hydrogen chloride (HCl) gas at 430–475°C, producing hydrogen gas (H₂).
  • Hydrolysis: Copper chloride (CuCl₂) reacts with superheated steam at 400°C to form copper oxychloride (Cu₂OCl₂) while regenerating HCl gas.
  • Oxygen Production: Copper oxychloride is heated to about 500°C using FBTR process heat, releasing oxygen gas (O₂) and producing cuprous chloride (CuCl).
  • Electrochemical Cycle: CuCl undergoes low-voltage electrolysis to regenerate copper (Cu) and copper chloride (CuCl₂), completing the closed cycle.

Key Features of the Kalpakkam Facility:

  • Powered by FBTR: Uses process heat from the Fast Breeder Test Reactor (FBTR) at Kalpakkam, India’s only operational sodium-cooled fast reactor.
  • Lower Temperature Requirement: The Cu–Cl cycle requires a maximum temperature of only 530°C, compared to over 850°C for the Sulfur–Iodine cycle.
  • Low Electricity Consumption: The electrolysis stage operates at just 0.5–1.0 volts, significantly lower than conventional water electrolysis (1.23 volts or more).
  • Round-the-Clock Operation: Unlike solar- or wind-based hydrogen production, the nuclear-powered system provides continuous, weather-independent hydrogen production.

Key Applications:

  • Decarbonizing Heavy Industries: Clean hydrogen can replace fossil-fuel-based gray hydrogen in steel, oil refining, and chemical industries, reducing carbon emissions.
  • Green Fertilizer Production: Provides carbon-free hydrogen for producing green ammonia, strengthening India’s fertilizer production and food security.
  • Clean Transport and Energy Storage: Supplies hydrogen for fuel-cell vehicles, shipping, aviation, and large-scale renewable energy storage.